Chlorite

 Smith College - Geology 222b - Petrology

Petrographic Data File

Chlorite
Property
Value
Comments
Formula (Mg, Al, Fe)3 (Si,Al)4O10(OH)2.(Mg,Al,Fe)3(OH)6


There are many compostional variations of chlorite where substitution of Mg, Al, Fe2+ and Fe3+ in the octahedral sheets and substitution of Al3+ and Si4+ in the tetrahedral sheets can occur. Common variations include clinochlore, pennine, prochlorite, and chamosite.

 

Crystal System monoclinic Some triclinic varieties
Crystal Habit Pseudohexagonal tabular crystals;commonly foliated, fibrous, granular, earthy or massive; twins on (001) Twinning is common but often difficult to recognize
Cleavage

perfect cleavage on {001}

 
Color/Pleochroism

colorless-pale green;
Pleochroic

 
Optic Sign Biaxial positive/negative

May be positive or negative based on composition and variety

2V 0-60 (positive)
0-40 (negative)
 
Optic Orientation X or Z^a=0-9o
Y=b
optic plane (010)

length fast (postive)
length slow (negative)

Refractive Indices

alpha=1.55-1.67
beta =1.55-1.69
gamma =1.55-1.69

 
Max Birefringence rarely above first-order white or yellow Chlorite commonly exhibits anomalous birefringence. Brown colors are typical of optically postive crystals, whereas blue and purple colors are typical of optically negative crystals.
Extinction Inclined  
Distinguishing Features Green under plane polarized light, pleochroic, anomalous interference colors, weak birefringence, micaceous
Occurrence

Chlorite is an important constituent of many contact and regional metamorphic rocks of low to medium grade, usually with temperatures of to 400 degrees C and pressures up to a few Kb. It also found in amygdules, fractures in altered volcanic rocks, hydrothermal vein deposits and soils.

Chlorite is often found with biotite, garnet, staurolite, andalusite, muscovite, chloritoid, and cordierite in pelitic rocks. In mafic rocks, it occurs with talc, serpentine, actinolite, hornblende, epidote, and garnet. It can also be found with feldspars, quartz, calcite, dolomite, olivine, plagioclase, rutile, ilmenite, titanite, magnetite, chromite, sulfides, zircon, and zeolites.

Chlorite forms by the alteration of mafic minerals such as pyroxenes, amphiboles, biotite, staurolite, cordierite, garnet, and chloritoid. Chlorite can also occur as a result of hydrothermal alteration of any rock type, where recrystallization of clay minerals or alteration of mafic minerals produce chlorite.

References and Links

Nesse, William D., 1986, Introduction to Optical Mineralogy: New York, Oxford University Press, 325 p.

UCLA Mineral Library

Editors Sarah Cadieux (MHC '08), Katherine Kravitz ('11)

 
Photomicrograph of chlorite in plane polarized light. Click the image to view a rollover image from plane polarized light to cross polarized light. Note the anolmalous interference depicted by the distinct green and brown colors in cross polarized light.
Photomicrograph of chlorite in plane polarized light. Click the image to view a rollover image from plane polarized light to cross polarized light. Note the anolmalous interference depicted by the distinct green and brown colors in cross polarized light.
Photomicrograph of chlorite in plane polarized light. Click the image to view a rollover image illustrating pleochroism from light green to light brown.


Return to Petrography Index