Smith College - Geology 222b - Petrology

Petrographic Data File

Titanite
A.K.A. Sphene
Property
Value
Comments
Formula CaTiOSiO4  
Crystal System Monoclinic (2/m) Beta = 119.9°
Crystal Habit Wedge-, and elongated rhomb-shaped crystals are common. Grains typically are not apparent in hand specimens. Simple twins may occur on {100}.

Diamond-shaped cross-sections can be seen in thin sections. Titanite has very high positive relief.

H=5-51/2

Cleavage Distinct prismatic ceavage {110} may control grain orientation. Uneven fracture. Brittle. Partings parallel to twins may be more prominent than cleavage
Color/Pleochroism

Tan-brown color. Nonpleochroic to weakly pleochroic:

x almost colorless
y pale yellow
z brownish

Color appears the same in plane and crossed polars
Optic Sign Biaxial (+)
2V 20-40°  
Optic Orientation

X /\ a=-6° to -21°
Y=b
Z /\ c=36-51°

 
Refractive Indices
alpha = 
beta = 
gamma = 

1.843-1.950
1.970-2.034
1.943-2.110

Max Birefringence 0.100-0.192 Birefringence is high order white which does not contribute to or alter the brown color of titanite.
Elongation cannot be easily determined  
Extinction Because of high dispersion, some grains do not extinguish completely.  
Dispersion  r > v Optic axis dispersion is very strong, inclined dispersion in weak.
Distinguishing Features Very High Relief. Extreme birefringence; same brownish color in plane and crossed polars. Diamond/wedge-shaped crystal habit
Occurrence Titanite is a common accessory in many igneous and metamorphic rocks, of which it can be the dominent Ti-bearing contituent. Titanite also occrs as detrital grains in the heavy mineral fraction of clastic sediments.
Editors Sarah Pistone ('06), Janelle McAtamney ('07)
Sources

Philpotts, Anthony R., 1989. Petrogrophy of Igneous and         Metamorphic Rocks. Waveland Press, Inc.: Prospect Heights,         Illinois. 61 p.
Nesse, William D., 2000. Introduction to Mineralogy. Oxford         University Press: New York, NY. 322 p.
MacKenzie W.S., and Guilford C., 1980. Atlas of rock-forming         minerals in thin section. Halsted Press: New York, NY. 97p.


 
Titanite (Sphene) grain under plane polarized light.
Photograph of a Titanite grain taken in plane polarized light (click for rollover image).
WWW Images http://tectonics.geo.ku.edu/images/titanite.gif


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