Smith College - Geology 222b - Petrology

Petrographic Data File

Cordierite
Property
Value
Comments
Formula Mg2Al3[AlSi5]O18 Fe2+ can substitute for Mg in octahedral sites, although most cordierite is fairly Mg rich. Fe3+ may substitute for Al.
Crystal System Orthorhombic (pseudohexagonal)
Crystal Habit Anhedral to to highly irregular porphyroblastic grains, less common as hexagonal prismatic crystals. Lamellar and cyclic twins common. Often uncludes numerous inclusions of quartz, opaque grains, and other minerals. Twinning more common in high-grade metamorphic rocks.
Cleavage

Fair cleavage on {010} and poor cleavage on {100} and {001}

Not usually obvious in hand sample or thin section. Subconchoidal fracture. Brittle.
Color/Pleochroism

Gray, grayish blue, blue, or indigo blue.

X = colorless, pale yellow, pale green; Y = pale blue to violet; Z= pale blue

In thin section: Colorless to very pale blue; darker with increasing Fe content. Usually no pleochrosim, though grain mounts may be distinclty pleochroic.
Optic Sign Biaxial (+ or -) Rarely biaxial (+).
2V 35-106°

Mostly biaxial (-) with 2V between 40 and 90°. High water and Na content yield lower 2V angles.

Optic Orientation X = c, Y = a, Z = b Elongate crystals are length fast.

Refractive Indices

alpha = 1.527-1.560
beta = 1.532-1.574
gamma = 1.537-1.578
delta = 0.005-0.017

 
Max Birefringence 0.005-0.017 Low birefringence yields first-order white/gray/yellow interference colors.
Extinction Parallel   
Dispersion r < v Weak.
Distinguishing Features Resembles quartz, bur more distinctly blue. Corundum is harder. Twinned cordierite resembles plagiclase in thin section, but plagioclase has more distinct cleavage and lacks radial twinning. Yellowish, pleochroic halos around radioactive minerals such as zircon are quite common. Typically contains small, opaque inclusions. Hardness = 7.
Alteration Cordierite is readily altered to pinite, a fine-grained greenish or yellowish aggregate of chlorite, muscovite and other silicates. The alteration may develop along cracks and grain margins.
Occurrence

Cordierite is a common mineral in medium and high-grade pelitic metamorphic rocks. It is also common as porphyroblasts in hornfels found in contact metamorphic zones. Favored by low pressures or high temperatures. It is rare in igneous rocks, and may result form the assimilation of aluminous sediments.

Associated with chlorite, andalusite, sillimanite, kyanite, staurolite, muscovite, biotite, and chloritoid. Granite, pegmatite, gabrros, and andesite infrequently contain cordierite.

Editor Christina Gooch ('07)
References Nesse, William D., 2000. Introduction to Mineralogy. Oxford University Press, New York, 442 p.

 

Photomicrograph of cordierite in plane polarized light. wollastonite in plane light. The cordierite is colorless in this thin section, with many visible inclusions. (Click to enlarge)

Thin section: RUP85T-75

Photomicrograph of cordierite in plane polarized light, rotated 90° from above picture. Notice the pleochroic yellowish halos around some of the inclusions. (Click to enlarge and to see image through crossed polars)


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